Mio Aoyama

A short, blonde 16 year old girl from Majima Academy. An elitist with an imperious and disdainful pride, she is the daughter of the President of Aoyama Central Industries. As Keima's second target, Keima at first believes he can easily win her heart due to Mio displaying typical Tsundere characteristics but upon he and Elsie secretly following her home, they find she isn't what they expected. Unknown to the public and her school, Mio family fortune has fallen after her father passed away where she and her mother now lives in a shabby apartment. However, she remains prideful and refuses to stop pretending to be still rich. In order to get close to Mio, Keima, who is the only one she knows from school who knows her secret, becomes her chauffeur after her old chauffeur Morita quits over her prideful behavior, where he rides her to school in various Cycle rickshaws made by Elsie. Mio at first harshly treats him but slowly takes a liking with Keima. After taking Mio to a party for the rich, Keima confronts her with the truth that she acts rich not out of pride but love for her late father as she can't accept his death but convinces her to accept the past and move on as this is want her father would want, which makes Mio falls for Keima as he cares about her which allows him to kiss her and forces the spirit out.
After these events, Mio has accepted her father passing and her family's financial situation yet still acts prideful and is interested with Keima. When Keima encounters Mio again in Yui's body, she is now working at a bakery to help her mother. Due to her memories being modified, Mio is unsure and thinks Morita went with her to that party that night. Seeing Mio getting better, Keima wishes her good luck which Mio finds familiar.
The cause of Mio's negative emotions was her refusal to accept her father's death and letting go of the past.
Her surname is derived from Aoyamachō Station (青山町駅 Aoyamachō-eki?). Also, Mio originally appeared in Wakaki's one-shot prototype Make Love?! God!! (恋して?! 神様!! Koishite?! Kami-sama!!?) with the surname "Tsumagawa".

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